SHELL OIL CO -- 01108, FORMULASHELL REGULAR GASOLINE (SUPDAT)  -- 9130-00N084620
<pre>=====================  Product Identification  =====================

Product ID:01108, FORMULASHELL REGULAR GASOLINE (SUPDAT)
MSDS Date:01/25/1996
FSC:9130
NIIN:00N084620
=== Responsible Party ===
Company Name:SHELL OIL CO
Box:4320
City:HOUSTON
State:TX
ZIP:77210
Country:US
Info Phone Num:713-241-4819
Emergency Phone Num:713-473-9461;800-424-9300(CHEMTREC)
CAGE:SHELO
=== Contractor Identification ===
Company Name:SHELL OIL CO
Box:4320
City:HOUSTON
State:TX
ZIP:77210-5000
Country:US
Phone:713-473-9461/713-241-2252
CAGE:SHELO
Company Name:SHELL OIL COMPANY
Address:Box:2463
City:HOUSTON
State:TX
ZIP:77210
Country:US
Phone:800-231-6950
CAGE:54527

=============  Composition/Information on Ingredients  =============

Ingred Name:ALKANES, CYCLOALKANES, ALKENES AND AROMATIC HYDROCARBONS
RTECS #:9999999ZZ
Fraction by Wt: BALANCE
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:XYLENE (SARA 313) (CERCLA)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 0-25%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 0-25%
OSHA PEL:200 PPM; Z-2
ACGIH TLV:S, 50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:BENZENE (SARA 313) (CERCLA)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: 0-4%
OSHA PEL:SEE 1910.1028
ACGIH TLV:10 PPM; A2
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS

Ingred Name:HEXANE (N-HEXANE) (CERCLA)
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: 0-3%
OSHA PEL:500 PPM
ACGIH TLV:50 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Ingred Name:ETHYL ALCOHOL (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
Fraction by Wt: </=10%
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM

Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA 313)
CAS:95-63-6
RTECS #:DC3325000
Fraction by Wt: 0-5%
OSHA PEL:25 PPM
ACGIH TLV:25 PPM

Ingred Name:CYCLOHEXANE (SARA 313) (CERCLA)
CAS:110-82-7
RTECS #:GU6300000
Fraction by Wt: 0-1%
OSHA PEL:300 PPM
ACGIH TLV:300 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:ETHYL BENZENE (SARA 313)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 0-3%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/125 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:NAPHTHALENE (SARA 313) (CERCLA)
CAS:91-20-3
RTECS #:QJ0525000
Fraction by Wt: 0-1%
OSHA PEL:10 PPM
ACGIH TLV:10 PPM/15 STEL
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS

Ingred Name:SUPDAT: AVOIDED AS EVEN SM QTYS MAY RSLT IN ASPIR PNEUM.
    LIQ IS READILY ABSORBED & MAY PRDCE CNS DEPRESS. PRLNGD(ING 12)
RTECS #:9999999ZZ
Other REC Limits:9999999ZZ

Ingred Name:ING 11: & RPTD EXPOS MAY PRDCE LIVER DMG. SIGNS & SYMPS:
    IRRIT AS NOTED ABOVE. EARLY TO MOD CNS DEPRESS MAY BE (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12: EVID BY GIDD, HDCH, DIZZ & NAUS; IN EXTREME CASES,
    UNCON & DEATH MAY OCCUR. ASPIR PNEUM MAY BE EVID BY (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13: COUGH, LABORED BRTHG & CYANOSIS(BLUISH SKIN); IN
    SEV CASES DEATH MAY OCCUR. KIDNEY DMG MAY BE EVID BY (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14: CHANGES IN URINE OUTPUT, URINE APPEAR/EDEMA(SWELL
    FROM FLUID RETENTION). LIVER DMG MAY BE EVID BY LOSS (ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15: OF APPETITE, JAUNDICE(YELLOWISH SKIN COLOR) &
    SOMETIMES PAIN IN UPPER ABDOM ON RIGHT SIDE. OTHER HLTH (ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16: EFTS: IARC HAS DETERM GASOLINE IS POSS CARCIN TO
    HUMANS(GRP 2B). CHRONIC INHAL EXPOS TO UNLEADED MOTOR (ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17: GASOLINE, HAS PRDCED KIDNEY & LIVER CANCERS IN SOME
    LAB RODENTS. INTENTIONAL ABUSE, MISUSE/OTHER MASSIVE(ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18: EXPOS TO ETHANOL MAY RSLT IN MULTIPLE ORGAN DMG
    &/OR DEATH. ETHANOL INGEST DURING PREGNANCY HAS BEEN (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19: RPTD TO CAUSE BIRTH DEFECTS IN SOME INFANTS. IARC
    RPTS ETHANOL TO BE CARCIN. ETHYL BENZENE HAS BEEN (ING 21)
RTECS #:9999999ZZ

Ingred Name:ING 20: SHOWN TO CAUSE CANCER IN LAB ANIMALS. SUPPLEMENTAL
    HLTH INFO: CONT NEHC FOR MORE SPECIFIC INFORMATION .
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC: SPONT KEEP HEAD BELOW HIPS TO PVNT ASPIR OF
    LIQUID INTO LUNGS. GET MED ATTN. NOTE TO PHYS: (ING 23)
RTECS #:9999999ZZ

Ingred Name:ING 22: FOR MORE SPECIFIC INFORMATION CONT NEHC .
RTECS #:9999999ZZ

Ingred Name:SPILL PROC: BE USEFUL IN SUPPRESSING VAP CLOUD; CNTN
    RUN-OFF. FOR MORE INFORMATION CONT NEHC .
RTECS #:9999999ZZ

Ingred Name:OTHER PREC: STATIC BUILDUP, PLACE APPRVD CNTNR ON GROUND.
    FOR MORE INFORMATION CONT NEHC .
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50: (ORAL,RAT) >5 G/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:YES    IARC:YES	  OSHA:YES
Health Hazards Acute and Chronic:TOLUENE APPEARS ON NAVY LISTING OF
    OCCUP CHEM REPROD HAZARDS. SEEK CONSULTATION FROM APPROP HLTH
    PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO & SAFE HNDLG &
    EXPOS INFO . ACUTE: EYE CONT: IRR ITATING. SKIN: PRLNGD & RPTD LIQ
    CONT CAN CAUSE DEFAT & DRYING OF SKIN RSLTING IN SKIN IRRIT & DERM.
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE: IARC MONO, SUPP, VOL 7, PG 120,
    1987: GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: KNOWN TO BE
    CARCIN.(SUPDAT)
Effects of Overexposure:HLTH HAZ: INHAL: MAY CAUSE IRRIT TO NOSE,
    THROAT & RESP TRACT & ADDNLY, MAY PRDCE LIVER & KIDNEY DMG. HIGH
    VAP CONCS MAY PRDCE CNS DEPRESS. PRLNGD & RPTD EXPOS TO BENZENE MAY
    CAUSE SERIOUS INJURY TO B LOOD FORMING ORGANS & IS LINKED TO LATER
    DEVELOPMENT OF ACUTE MYELOGENOUS LEUKEMIA. INGEST: MAY BE HARMFUL
    OR (SUPDAT)
Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN, &
    RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOS TO THIS PROD.
    IMPAIRED LIVER & KIDNEY FUNCTION(S) FROM PREEXISTING DISORDERS MAY
    BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.

=======================  First Aid Measures  =======================

First Aid:EYE: FLUSH W/WATER FOR @ LST 15 MINS WHILE HOLDING EYELIDS
    OPEN. GET MED ATTN. SKIN: FLUSH W/WATER WHILE REMOVING CONTAMD
    CLTHG & SHOES. FOLLOW BY WASHING W/SOAP & WATER. DO NOT REUSE
    CLTHG/SHOES UNTI L CLEANED. IF IRRIT PERSISTS, GET MED ATTN. INHAL:
    REMOVE TO FRESH AIR & PROVIDE OXYG IF BRTHG IS DFCLT. GIVE ARTF
    RESP IF NOT BRTHG. GET MED ATTN. INGEST: DO NOT INDUCE VOMIT. IF
    VOMIT OCCURS(ING 22)

=====================  Fire Fighting Measures  =====================

Flash Point Method:TCC
Flash Point:-40F,-40C
Lower Limits:1.3%
Upper Limits:7.6%
Extinguishing Media:WATER FOG, FOAM, DRY CHEM/CO*2. DO NOT USE DIRECT
    STREAM OF WATER. PROD WILL FLOAT & CAN BE REIGNITED ON SURF OF
    WATER.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . DANGER.
    EXTREMELY FLAMM. CLEAR FIRE AREA OF UNPROTECTED PERS & ISOLATE.
    COOL FIRE EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR ACCUM IN LOW AREAS &
    TRAVELING ALONG GROUND AWAY FROM HNDLG SITE. DO NOT WELD,
    HEAT/DRILL ON/NEAR CNTNRS. HOWERVER, IF EMER SITUATIONS (SUPDAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:ELIM ALL IGNIT SOURCES. HNDLG EQUIP MUST BE
    GROUNDED TO PVNT SPK. LG SPILL: ISOLATE HAZ AREA & DENY ENTRY TO
    UNNEC PERS. WEAR APPROP NIOSH APPRVD RESP & PROT CLTHG. SHUT OFF
    SOURCE OF LEAK ONLY IF SAF E TO DO SO. DIKE & CNTN. WATER FOG MAY
    (ING 24)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:AVOID HEAT, SPK, OPEN FLAME, INCL
    PILOT LIGHTS, & STRONG OXIDIZING AGENTS. USE EXPLOSION-PROOF VENT
    TO PVNT VAP ACCUM. HARMFUL/FATAL IF SWALLOWED.
Other Precautions:ALL HNDLG EQUIP MUST BE GROUNDED TO PVNT SPARKING. DO
    NOT SIPHON GASOLINE BY MOUTH. WARNING: FLOW OF GASOLINE THRU PUMP
    NOZZ CAN PRDCE STATIC ELEC, WHICH MAY CAUSE FIRE IF GASOLINE IS
    PUMPED INTO UNGR OUNDED GASOLINE CNTNR. TO AVOID (ING 25)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:AVOID BRTHG VAP. UNDER CNDTNS OF POTNTL HIGH
    EXPOS, USE OF NIOSH APPRVD RESP IS REC. PER 29CFR 1910.134/29CFR
    1910.1028 USE EITHER NIOSH APPRVD ATMMOSPHERE-SUPPLYING
    RESP/AIR-PURIFYING RESP FOR ORGANI C VAPORS.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
    VAPOR CONCENTRATIONS.
Protective Gloves:NITRILE RUBB, PVA, VITON/NEOPRENE.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . CLTHG
    PROVIDED BY NITRILE RUBB, POLYVINYL ALCOHOL OR VITON/NEOPRENE.
Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING,
    SMKNG/USING TOILET FACILITIES. LAUNDER CONTAMD CLTHG BEFORE REUSE.
Supplemental Safety and Health
MFR TRADE NAME/PART NO: WITH ETHANOL (CONVENTIONAL AND RFG). SPEC GRAV:
    0.72-0.76 (H*2O=1). EXPLO HAZ: REQ DRILLING, ONLY TRAINED EMER PERS
    SHOULD DRILL. EXPLAN OF CARCIN: OSHA REGULATED:CFR 29 1910.1 028.
    EFTS OF OVEREXP: FATAL IF SWALLOWED. INGEST MAY RSLT IN VOMIT;
    ASPIR (BRTHG) OF VOMITUS INTO LUNGS MUST BE (ING 11)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:>100F,>38C
Vapor Pres:7-14.5 PSI
Vapor Density:3.5
Spec Gravity:SUPDAT
Evaporation Rate &amp; Reference:NOT KNOWN
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BRONZE COLOR; CLEAR AND BRIGHT LIQUID. HYDROCARBON
    ODOR.
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
AVOID HEAT, SPARKS, OPEN FLAMES AND STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES AND STRONG
    OXIDIZING AGENTS. PREVENT VAPOR ACCUMULATION.
Hazardous Decomposition Products:CARBON MONOXIDE & OTHER UNIDENTIFIED
    ORGANIC COMPOUNDS CAN BE FORMED UPON COMBUSTION.

====================  Disposal Considerations  ====================

Waste Disposal Methods:UNDER EPA -RCRA (40 CFR 261.21). IF THIS PROD
    BECOMES WASTE MATL, IT WOULD BE IGNITABLE HAZ WASTE, HAZ WASTE
    NUMBER D001. REFER TO LATEST EPA FEDERAL, STATE OR LOCAL REGS
    REGARDING PROPER DISP. FOR MO RE SPECIFIC INFORMATION CONT NEHC .

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 disclaims all liability for its use.  Any person utilizing this
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