MALLINCKRODT INC -- POTASSIUM NITRATE -- 6810-00N068994
===================== Product Identification ===================== Product ID:POTASSIUM NITRATE MSDS Date:10/29/1993 FSC:6810 NIIN:00N068994 === Responsible Party === Company Name:MALLINCKRODT INC Box:800 City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:314-539-1600 Emergency Phone Num:314-539-1600 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM NITRATE CAS:7757-79-1 RTECS #:TT3700000 OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: 3450 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL: IRRIT THE RESP TRACT.SYMPS MAY INCL COUGHING, SHORTNESS OF BRTH. INGEST: MAY CAUSE GI & ABDOM PAINS. PURGING & DIURESIS CAN BE EXPECTED. RARE CASES OF NITRATES BEING CONVERTED TO MORE TOX NITRI TES HAVE BEEN RPTD, MOSTLY W/INFANTS. SKIN/EYE: CAUSES IRRIT; SYMPS INCLG REDNESS, ITCHING & PAIN. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:CHRONIC: UNDER SOME CIRCUMSTANCES METHEMOGLOBINEMIA OCCURS IN PERS WHEN NITRATE IS CONVERTED BY BACTERIA IN STOM TO NITIRITE. NAUS, VOMIT, DIZZ, RAPID HEARTBEAT, IRREG BRTHG, CONVULS, COMA & DEATH CAN OCCUR SHOULD CONVERSION TAKE PLACE. CHRONIC EXPOS TO NITRITES MAY CAUSE ANEMIA & ADVERSE EFTS TO KIDNEYS. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. GET MED ATTN FOR ANY BRTHG DFCLTY. INGEST:INDUCE VOMIT IMMED AS DIRECTED BY MED PERS. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS. SKIN:REMOVE ANY CONTAMD CLTHG. WIPE OFF EXC ESS FROM SKIN. WASH SKIN W/SOAP & WATERFOR AT LEAST 15 MIN. GET MED ATTN IF IRRIT DEVEL/PERSISTS. EYE:WASH W/PLENTY OF WATER FOR AT LEAST 15 MINS LIFTING LOWER & UPPER EYELIDS OCCASNLY. GET(SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTING SURROUNDING FIRE. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CNTNRS COOL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. THIS OXIDIZING MATLS CAN INCR FLAMM OF ADJACENT COMBUST MATL. Unusual Fire/Explosion Hazard:NITRATES MAY EXPLODE WHEN SHOCKED, EXPOSED TO HEAT/FLAME/BY SPONT CHEM RXN. NOT COMBUST, BUT IS STRONG OXIDIZER & ITS HEAT OF RXN W/REDUCING AGENTS/(SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP SPILL IN MANNER THAT DOES NOT DISPERSE DUST INTO AIR. PICK UP SPILL FOR RECOVERY/DISP & PLACE IN CLSD CNTNR. (IF SPILLED MATL IS INTERMIXED W/COMBUST IT MAY BE DESIRABLE TO WET W/WATER & MIX W/WET SAND BEFORE PICK-UP FOR DISP). Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLSD CNTNR, STORED IN COOL, DRY, VENT AREA. PROT AGAINST PHYSICAL DMG. SEPARATE FROM COMBUST, ORG/OTHER READILY OXIDIZABLE MATLS. Other Precautions:DO NOT STORE ON WOODEN FLOORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR CNDTNS OF USE WHERE EXPOS TO DUST IS APPARENT, A NIOSH/MSHA DUST/MIST RESP MAY BE WORN. FOR EMERGENCIES, A NIOSH/MSHA APPRVD SCBA MAY BE NECESSARY. Ventilation:LOC EXHST SYS WHICH CAPTURES THE CONTAM AT ITS SOURCE IS RECOM TO PVNT DISPERSION OF CNTAMD INTO WORKROOM AIR. Protective Gloves:RUBBER/NEOPRENE GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS. Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER. IMPERVIOUS BOOTS, APRON/COVERALLS AS NEEDED IN AREAS OF UNUSUAL EXPOS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health BP: DECOMPOSES @ 400C(752F). EXPLO HAZ: COMBUSTIBLES MAY CAUSE IGNITION. FIRST AID PROC: MED ATTN IMMED. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SUPDAT Melt/Freeze Pt:M.P/F.P Text:631F,333C Spec Gravity:2.1 Solubility in Water:36 GM/100 ML WATER Appearance and Odor:WHITE CRYSTALS. ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HEAVY METALS, PHOSPHITES, ORG CMPDS, CARBONACEOUS MATLS, STRONG ACIDS & MANY OTHER SUBSTANCES. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE & STORAGE. Hazardous Decomposition Products:MAY EMIT OXIDES OF NITROGEN AND OXIDES OF POTASSIUM WHEN HEATED TO DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE DELIVERED TO AN APPRVD WASTE DISP FACILITY. ENSURE COMPLIANCE W/LOCAL, STATE & FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.