MEDICAL CHEMICAL CORP. -- GRAM'S DECOLORIZER (ACETONE/ALCOHOL), 304A -- -
===================== Product Identification ===================== Product ID:GRAM'S DECOLORIZER (ACETONE/ALCOHOL), 304A MSDS Date:03/30/1995 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:MEDICAL CHEMICAL CORP. Address:1909 CENTINELA AVENUE City:SANTA MONICA State:CA ZIP:90404 Country:US Info Phone Num:(310) 829-4304 Emergency Phone Num:(800)424-9300 Preparer's Name:P. B. Chemtrec Ind/Phone:(800)424-9300 CAGE:TO718 === Contractor Identification === Company Name:MEDICAL CHEMICAL CORP. Address:1909 CENTINELA AVENUE Box:City:SANTA MONICA State:CA ZIP:90404 Country:US Phone:(310) 829-4304 CAGE:TO718 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL CAS:64-17-5 RTECS #:KQ6300000 = Wt:0. = Vol:64. OSHA PEL:1900 MG/M3;1000 PPM ACGIH TLV:1880 MG/M3;1000 PPM Ingred Name:ISOPROPANOL CAS:67-63-0 RTECS #:NT8050000 = Wt:0. = Vol:3.6 OSHA PEL:400 PPM ACGIH TLV:400 PPM Ingred Name:METHYL ALCOHOL CAS:67-56-1 RTECS #:PC1400000 = Wt:0. = Vol:3.6 OSHA PEL:200 PPM (SKIN) ACGIH TLV:200 PPM (SKIN) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETONE CAS:67-64-1 RTECS #:AL3150000 = Wt:0. = Vol:25. OSHA PEL:1000 PPM ACGIH TLV:750 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:HEALTH HAZARDS (ACUTE & CHRONIC): METHANOL IS A CUMULATIVE POISON & DEATH HAS BEEN REPORTED FOR INGESTION OF LESS THAN 30 ML. CAUSES CNS DEPRESSION, HEADACHE, INTOXICATION, DILATION OF THE PUPILS, CON VULSIONS, NAUSEA & DIZZINESS. UNCONCIOUSNESS AND DEATH MAY RESULT. METHANOL INTOXICATION MAY PRODUCE VISUAL DISTURBANCES AND BLINDNESS. Effects of Overexposure:CNS DISTURBANCE, DIZZINESS, PHOTO PHOBIA, HEADACHE, STUPOR, COMA AND DEATH. Medical Cond Aggravated by Exposure:IMPAIRED KIDNEY & LIVER FUNCTION MAY BE AGGRAVATED BY EXPOSURE TO ALCOHOLS. PRE-EXISTING EYE, SKIN & RESPIRATORY CONDITIONS MAY ALSO BE AGGRAVATED. METHANOL HAS SHOWN GENETIC TOXICITY IN SOME ANIMALS. ======================= First Aid Measures ======================= First Aid:IN CASE OF EYE CONTACT, FLUSH WITH WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. IN CASE OF SKIN CONTACT, REMOVE CONTAMINATED CLOTHING & FLUSH WITH WATER. GET MEDICAL ATTENTION IF IRRITATIO N PERSISTS. IN CASE OF INGESTION DO NOT INDUCE VOMITING IF PATIENT IS UNCONCIOUS OR EXTREMELY DROWSY. OTHERWISE, ADMINISTER 2 GLASSES OF WATER & INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION EVEN I F SYMPTOMS IMPROVE. INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING. CONTACT PHYSICIAN IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=24.C, 75.2F Lower Limits:3% (ETHANOL) Upper Limits:19% (ETHANOL Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT . WATER IS INEFFECTIVE AGAINST ALCOHOL FIRES BUT MAY BE USED TO COOL ADJACENT CONTAINERS. Unusual Fire/Explosion Hazard:PYROLYSIS WILL RELEASE TOXIC GASES SUCH AS CARBON MONOXIDE AND METHANOL. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, ABSORB WITH SUITABLE ABSORBENT (SUCH AS PAPER TOWELS) AND DISPOSE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORAGE: STORE AT ROOM TEMPERATURE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE EXPOSURE OF CONCERN . Ventilation:CHEMICAL FUME HOODS ARE RECOMMENDED FOR HANDLING METHANOLIC SOLUTIONS. Protective Gloves:PLASTIC OR RUBBER GLOVES IMPERVIOUS TO METHANOL ARE RECOMMENDED. Eye Protection:LABORATORY SAFETY GOGGLES OR SIMILAR PRODUCTS ARE RECOMMENDED. Other Protective Equipment:EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH WELL AFTER HANDLING ESPECIALLY BEFORE EATING OR SMOKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:=62.C, 143.6F B.P. Text:62-63C Vapor Pres:213 MM HG @ 25C Vapor Density:2 (AIR=1) Spec Gravity:0.8 Evaporation Rate & Reference:1(ETHANOL = 1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS SOLUTION WITH CHARACTERISTIC ODORS OF ALCOHOL AND ACETONE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STORE AWAY FROM OXIDIZERS. Stability Condition to Avoid:HEAT AND FLAME. Hazardous Decomposition Products:PYROLYSIS WILL RELEASE TOXIC GASES SUCH AS CARBON MONOXIDE AND METHANOL. ==================== Disposal Considerations ==================== Waste Disposal Methods:THE PREFERRED DISPOSAL METHOD IS INCINERATION. MANY LOCALITIES RESTRICT AMOUNT OF ALCOHOL THAT MAY BE FLUSHED DOWN DRAIN. INSURE COMPLIANCE WITH ALL GOVERNMENT REGULATIONS. =================== MSDS Transport Information =================== Transport Information:D.O.T. SHIPPING NAME: ETHYL ALCOHOL. D.O.T. HAZARD CLASS: FLAMMABLE LIQUID. D.O.T. IDENTIFICATION NUMBER: NA1986. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.