MATHESON TRI-GAS, INC. -- DIETHYL DISULFIDE -- -
===================== Product Identification ===================== Product ID:DIETHYL DISULFIDE MSDS Date:Jan 24 1989 Kit Part:=== Responsible Party === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 Chemtrec Ind/Phone:18004249300 === Contractor Identification === Company Name:MATHESON TRI-GAS, INC. Address:959 ROUTE 46 EAST Box:City:PARSIPPANY State:NJ ZIP:07054-0624 Country:US Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE:Company Name:MATHESON TRI-GAS, INC. Address:530 WATSON STREET Box:City:WHITBY State:ZIP:L1N 5R9 Country:ONTARIO, CANADA Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON) 780-471-4036 CAGE: ============= Composition/Information on Ingredients ============= Ingred Name:DIETHYL DISULFIDE CAS:110-81-6 Fraction by Wt: 100.0% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:No IARC:No OSHA:No Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid: INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. SKIN CONTACT: Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. EYE CONTACT: Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. INGESTION: If a large amount is swallowed, get medical attention. ===================== Fire Fighting Measures ===================== Flash Point:No data available. Extinguishing Media:regular dry chemical, carbon dioxide, water, regular foam Large fires: Use regular foam or flood with fine water spray. Fire Fighting Procedures:Move container from fire area if it can be done without risk. Do not scatter spilled material with high-pressure water streams. Dike for later disposal. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. Unusual Fire/Explosion Hazard:Moderate fire hazard. ================== Accidental Release Measures ================== Spill Release Procedures:Stop leak if possible without personal risk. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Keep unnecessary people away, isolate hazard area and deny entry. Neutralizing Agent: ====================== Handling and Storage ====================== Handling and Storage Precautions:Store and handle in accordance with all current regulations and standards. Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any chemical cartridge respirator with organic vapor cartridge(s). Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s). Any air-purifying respirator with a full facepiece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full facepiece. Ventilation:Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. Protective Gloves:Wear appropriate chemical resistant gloves. Eye Protection:Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Other Protective Equipment:Wear appropriate chemical resistant clothing. Supplemental Safety and Health DIETHYL DISULFIDE: No occupational exposure limits established. ================== Physical/Chemical Properties ================== Boiling Pt:309 F (154 C) Melt/Freeze Pt:-152 F (-102 C) Vapor Pres:4.28 mmHg @ 25 C Vapor Density:4.22 Spec Gravity:0.9931 pH:Not available Evaporation Rate & Reference:Not available Solubility in Water:soluble Appearance and Odor:PHYSICAL STATE:liquid TEXTURE:oily ODOR:Not available Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:Stable at normal temperatures and pressure. Stability Condition to Avoid:Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials. Hazardous Decomposition Products:Thermal decomposition products: miscellaneous decomposition products Thermal decomposition products: miscellaneous decomposition products Conditions to Avoid Polymerization:Will not polymerize. =================== Toxicological Information =================== Toxicological Information:DIETHYL DISULFIDE: IRRITATION DATA: 500 mg/24 hour(s) skin-rabbit mild; 100 mg/24 hour(s) eyes-rabbit moderate TOXICITY DATA: 2030 mg/kg oral-rat LD50 LOCAL EFFECTS: Irritant: skin, eye ACUTE TOXICITY LEVEL: Moderately Toxic: ingestion ===================== Ecological Information ===================== Ecological:Not available ==================== Disposal Considerations ==================== Waste Disposal Methods:Dispose in accordance with all applicable regulations. =================== MSDS Transport Information =================== Transport Information:U.S. DEPARTMENT OF TRANSPORTATION: No classification assigned. ===================== Regulatory Information ===================== SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: Yes REACTIVE: No SUDDEN RELEASE: No SARA TITLE III SECTION 313 (40 CFR 372.65): Not regulated. Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY (29CFR1910.119): Not regulated. State Regulatory Information: California Proposition 65: Not regulated. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.