DU PONT E I DE NEMOURS & CO INC -- DU000025 FREON 22 -- 6830-00-290-4375
===================== Product Identification ===================== Product ID:DU000025 FREON 22 MSDS Date:06/03/1997 FSC:6830 NIIN:00-290-4375 === Responsible Party === Company Name:DU PONT E I DE NEMOURS & CO INC Address:1007 MARKET STREET Box:1635 City:WILMINGTON State:DE ZIP:19898 Country:US Info Phone Num:800-441-9442 Emergency Phone Num:800-424-9300 CHEMTREC Preparer's Name:ENGINEERING & SAFETY CAGE:18873 === Contractor Identification === Company Name:DU PONT E I DE NEMOURS AND CO INC PETROCHEMICALS DEPT Address:1251 BRANDYWINE BLDG Box:City:WILMINGTON State:DE ZIP:19898 Phone:302-773-5676 CAGE:73925 Company Name:E.I. DUPONT DE NEMOURS & CO Address:1007 MARKET STREET Box:City:WILMINGTON State:DE ZIP:19898 Country:US Phone:800-441-7515;800-441-9442 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:CHLORODIFLUOROMETHANE (SARA 313) (CERCLA) CAS:75-45-6 RTECS #:PA6390000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9596 Ozone Depleting Chemical:2 ===================== Hazards Identification ===================== LD50 LC50 Mixture:4-HOUR LC-50 (RAT): 220,000 PPM Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION OF HIGH CONCENTRATIONS OF VAPOR IS HARMFUL & MAY CAUSE HEART IRREGULARITIES, UNCONSCIOUSNESS OR DEATH. INTENTIONAL MISUSE OR DELIBERATE INHALATION MAY CAUSE DEATH WITHOUT WARNING. VAPOR RED UCES OXYGEN AVAILABLE FOR BREATHING & IS HEAVIER THAN AIR. LIQUID CONTACT CAN CAUSE FROSTBITE. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:SKIN-FROSTBITE, DEFATTING, DRYNESS. EYES-IRRITATION, DISCOMFORT, TEARING, BLURRING OF VISION. INHALED-DIZZINESS, HEADACHE, CONFUSION, INCOORDINATION, LOSS OF CONSCIOUSNESS, IRREGULAR HEART BEAT. Medical Cond Aggravated by Exposure:PRE-EXISTING DISEASES OF THE CANTRAL NERVOUS OR CARDIOVASCULAR SYSTEMS MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE OVEREXPOSURES. ======================= First Aid Measures ======================= First Aid:SKIN-FLUSH WITH LUKEWARM (NOT HOT!) WATER. CALL A PHYSICIAN IF FROSTBITE HAS OCCURED. INHALED-IMMEDIATELY REMOVE TO FRESH AIR. KEEP PERSON CALM. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GIVE OXYG EN IF BREATHING DIFFICULT. CALL A PHYSICIAN. EYES-IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. CALL A PHYSICIAN. INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:1170F Extinguishing Media:AS APPROPRIATE FOR COMBUSTIBLES IN AREA. EXTINGUISHANT FOR OTHER BURNING MATERIAL IN AREA IS SUFFICIENT TO STOP BURNING. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL FIRE FIGHTER'S PROTECTIVE GEAR. USE WATER TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:COMPRESSED GAS. CYLINDERS MAY EXPLODE IF EXPOSED TO FIRE. DECOMPOSITION MAY OCCUR. ================== Accidental Release Measures ================== Spill Release Procedures:USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. VENTILATE AREA, ESPECIALLY LOW OR ENCLOSED AREAS. REMOVE OPEN FLAMES. USE SCBA FOR LARGE SPILLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED AREA. DO NOT HEAT ABOVE 125F (52C). USE WITH SUFFICIENT VENTILATION TO EXPOSURE BELOW RECOMMENDED LIMITS. Other Precautions:PRODUCT SHOULD NOT BE USED OR ALLOWED TO BE PRESENT WITH HIGH CONENTRATIONS OF AIR ABOOVE ATMOSPHERIC PRESSURE. CONTACT W/CHLORINE OR OTHER STRONG OXIDIZING AGENTS SHOULD BE AVOIDED. LIQUIFIED GAS UND ER PRESSURE. CLOSE VALVE WHEN NOT IN USE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IAW 29 CFR 1910.134. Ventilation:NORMAL VENTILATION IS GENERALLY ADEQUATE. LOCAL EXHAUST USED FOR LARGE RELEASES; MECHANICAL FOR LOW OR ENCLOSED AREAS. Protective Gloves:IMPERVIOUS. Eye Protection:CHEMICAL SPLASH GOGGLES. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH HANDS BEFORE EATING, DRINKING, OR SMOKING. Supplemental Safety and Health NSN IS FOR PRODUCT BY ITSELF (PER TIR). NSN FOR CYLINDER ALONE: 8120-01-348-3119. NSN FOR FILLED CYLINDER IS 6830-00-782-3930. ACTUAL ITEM MANAGER IS CODE JDC (LOCAL PURCHASE) PER TIR-NOT CX (DSCR)(PL ACED THERE JUST TO FILL IN BOX!). ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:41.4F,5.2C Decomp Temp:Decomp Text:1170F,632C Vapor Pres:7809 Vapor Density:3.0 Spec Gravity:1.184 Evaporation Rate & Reference:>1 (CCL4=1) Solubility in Water:SLIGHT Appearance and Odor:CLEAR, COLORLESS LIQUIFIED GAS; SLIGHT ETHERAL ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI OR ALKALINE EARTH METALS, EG. ALUMINUM, ZINC, BERYLIUM, ETC. Stability Condition to Avoid:AVOID OPEN FLAMES AND HIGH TEMPERATURES. Hazardous Decomposition Products:TOXIC FUMES OF HYDROCHLORIC & FLUORIC ACIDS AND POSSIBLY CARBONYL HALIDES. Conditions to Avoid Polymerization:POLYMERIZATION WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY WITH LOCAL, STATE AND FEDERAL REGULATIONS. RECLAIM BY DISTILLATION OR REMOVE TO A PERMITTED WASTE DISPOSAL FACILITY. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.