DU PONT E I DE NEMOURS & CO INC -- HYVAR X HERBICIDE -- 6840-01-408-9079
===================== Product Identification ===================== Product ID:HYVAR X HERBICIDE MSDS Date:12/12/1996 FSC:6840 NIIN:01-408-9079 === Responsible Party === Company Name:DU PONT E I DE NEMOURS & CO INC Address:1007 MARKET STREET Box:1635 City:WILMINGTON State:DE ZIP:19898 Country:US Info Phone Num:800-441-7515/MSDS 302-992-3511 Emergency Phone Num:800-441-3637 Resp. Party Other MSDS Num.:DU003801 Chemtrec Ind/Phone:(800)424-9300 CAGE:18873 === Contractor Identification === Company Name:A-J CHEMICAL & EQUIPMENT Address:915 PLEASANT ST Box:City:RICHMOND State:VA ZIP:23223 Country:US Phone:804-737-8707 CAGE:0X818 Company Name:B AND G CHEMICAL AND EQUIPMENT CO INC Address:10539 MAYBANK ST Box:City:DALLAS State:TX ZIP:75220-2512 Country:US Phone:214-357-5741 Contract Num:SP0450-01-M-D720 CAGE:9L921 Company Name:E.I. DUPONT DE NEMOURS & CO Address:1007 MARKET STREET Box:City:WILMINGTON State:DE ZIP:19898 Country:US Phone:800-441-7515;800-441-9442 CAGE:18873 Company Name:EHRLICH J C CHEMICAL CO INC Address:500 SPRING RIDGE DR Box:City:READING State:PA ZIP:19612-3848 Country:US Phone:610-372-9700/FAX: 610-378-9744 Contract Num:SP0-450-01-M-D310 CAGE:8C885 Company Name:EHRLICH J C CHEMICAL CO INC Address:500 SPRING RIDGE DR Box:City:READING State:PA ZIP:19612-3848 Country:US Phone:610-372-9700/FAX: 610-378-9744 Contract Num:SP0450-99-M-C815 CAGE:8C885 Company Name:GOURMET INQUE LTD Address:191 STANLEY ST Box:City:ELK GROVE VILLAGE State:IL ZIP:60007-1555 Country:US Phone:847-296-6192/FAX: 800-542-1042 CAGE:0TNN7 Company Name:TIMBERLAND ENTERPRISES INC Address:140 ARKANSAS ST Box:557 City:MONTICELLO State:AR ZIP:71655 Country:US Phone:501-367-8561 Contract Num:SP0450-99-M-NC08 CAGE:1HB45 ============= Composition/Information on Ingredients ============= Ingred Name:BROMACIL (5-BROMO-3-SEC-BUTYL-6-METHYLURACIL) CAS:314-40-9 RTECS #:YQ9100000 = Wt:80. Other REC Limits:NONE RECOMMENDED OSHA PEL:1 PPM ACGIH TLV:10 MG/M3; 9596 Ingred Name:INERT INGREDIENTS = Wt:20. Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50: 2000 MG/KG (MALE RATS) Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:SKIN CONTACT MAY CAUSE IRRITATION OR RASH. EYE CONTACT MAY INITIALLY INCLUDE IRRITATION, TEARING OR BLURRING OF VISION. SIGNIFIGANT SKIN PERMEATION & SYSTEMIC TOXICITY AFTER CONTACT APPEARS UNLIKELY. THERE ARE NO REPORTS OF HUMAN SENSITIZATION. MAY IRRITATE EYES, NOSE & THROAT. CHRONIC: COMPOUND IS A MODERATE SKIN IRRITANT, IS A MILD EYE IRRITANT AND IS NOT A SKIN SENSITIZER. ANIMALS ACUTELY EXPOS ED VIA DERMAL ROUTE DEMONSTRATED NO CLINICAL SIGNS OF TOXICITY & NO GROSS TISSUECHANGES WERE OBSERVED. Explanation of Carcinogenicity:NONE OF COMPONENTS PRESENT IN MATERIAL AT CONCENTRATION EQUAL TO OR GREATER THAN 0.1% ARE LISTED BY IARC,NTP,OSHA,ACGIH AS CARCINOGEN. Effects of Overexposure:MAY IRRITATE EYES,NOSE,THROAT,SKIN. SKIN RASH; TEARING OR BLURRING OF VISION. Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= First Aid Measures ======================= First Aid:INHALED-NO SPECIFIC INTERVENTION IS INDICATED AS THE COMPOUND IS NOT LIKELY TO BE HAZARDOUS BY INHALATION. CONSULT A PHYSICIAN IF NECESSARY. SKIN CONTACT-WASH WITH PLENTY OF SOAP & WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. EYE CONTACT-FLUSH EYES WITH PLENTY OF WATER. CALL A PHYSICIAN IF IRRITATION PERSISTS. INGESTION-IMMEDIATELY GIVE 2 GLASSES OF WATER & INDUCE VOMITING. NEVER GIVE ANY THING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CARBON DIOXIDE (CO2). Fire Fighting Procedures:EVACUATE PERSONNEL TO SAFE AREA.WEAR SCBA. WEAR FULL PROTECTIVE EQUIPMENT. COOL TANK/CONTAINER WITH WATER SPRAY. RUNOFF FROM FIRE CONTROL MAY BE POLLUTION HAZARD. IF AREA HEAVILY EXPOSED TO FIRE & IF CONDITIONS PERMIT LET FIRE BURN ITSELF OUT, SINCE WATER MAY INCREASE CONTAMINATION HAZARD. Unusual Fire/Explosion Hazard:MAY BE IGNITED BY HEAT OR OPEN FLAMES. LIKE MOST ORGANIC POWDERS/CRYSTALS, UNDER SEVERE DUSTING CONDITIONS, MATERIAL MAY FORM EXPLOSIVE MIXTURES IN AIR. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE SPILL. SHOVEL OR SWEEP UP. IF SPILL AREA IS ON GROUND NEAR VALUABLE PLANTS OR TREES, REMOVE TOP 2 INCHES OF SOIL AFTER INITIAL CLEAN-UP. NOTE: REVIEW FIRE FIGHTING & HANDLING SECTIONS BEFORE CLEA N-UP. USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT DURING CLEAN-UP. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID BREATHING DUST. AVOID CONTACT WITH EYES, SKIN OR CLOTHES. WASH THOROUGHLY AFTER HANDLING. DO NOT STORE OR CONSUME FOOD, DRINK OR TOBACCO IN AREAS WHERE THEY MAY BECOME CONTAMINATED WITH THIS MAT ERIAL. Other Precautions:STORE PRODUCT IN ORIGINAL CONTAINER ONLY. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A WELL-VENTILATED AREA. DO NOT CONTAMINATE WATER, OTHER PESTICIDES, FERTILIZER, FOOD OR FEED IN STORAGE. DO NOT STORE OR CONSUME FOOD, DRINK OR TOBACCO IN AREAS WHERE THEY MAY BECOME CONTAMINATED WITH THIS MATERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SPECIFIED BY MANUFACTURER. Ventilation:USE ONLY WITH ADEQUATE VENTILATION. KEEP CONTAINER TIGHTLY CLOSED. Protective Gloves:WATERPROOF GLOVES. Eye Protection:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:LONG-SLEEVED SHIR, LONG PANTS, SHOES+SOCKS. PPE REQUIRED FOR EARLY ENTRY TO TREATED AREAS THAT'S PERMITTED UNDER WORKER PROTECTION STANDARD & INVOLVED CONTACT WITH ANYTHING THAT HAS BEEN TREATED. Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health EPA REGISTRATION NUMBER: 352-287. ================== Physical/Chemical Properties ================== HCC:T5 Vapor Density:0.53 G/CC pH:8.5- 9.5 Solubility in Water:WETTABLE Appearance and Odor:BEIGE SOLID (POWDER) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AMINES PARTICULARLY PRIMARY AMINES Stability Condition to Avoid:STABLE AT NORMAL TEMPERATURES AND STORAGE CONDITIONS. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. =================== Toxicological Information =================== Toxicological Information:ANIMAL DATA: ORAL LD50: 2000 MG/KG (MALE RAT); 1300 MG/KG (FEMALE RAT). SLIGHTLY TOXIC BY INGESTION. SKIN ABSORPTION LD50: >5000 MG/KG (RABBITS) SLIGHTLY TOXIC BY CONTACT. INHALATION 4 HR LC50: >4.8 M G/L (RATS). NO MORTALITIES OCCURRED ATTHIS CONCENTRATION. CONSIDERED SLIGHTLY TOXIC BY INHALATION. CHRONIC STUDIES-TECHNICAL BROMACIL: THE COMPOUND IS A MODERATE SKIN IRRITANT, IS A MILD TO MODERATE E YE IRRITANT, & IS NOT A SKIN SENSITIZER. RABBITS ACUTELY EXPOSED VIA DERMAL ROUTE DEMOSTRATED NO CLINICAL SIGNS OF TOXICITY, & NOT GROSS TISSUE CHANGES WERE OBSERVED AT THE HIGHEST PRACTICAL DOSE, 5,0 00 MG/KG. ===================== Ecological Information ===================== Ecological:AQUATIC TOXICITY.BROMACIL TECHNICAL 72 HOUR LC50,RAINBOW TROUT:38 PPM. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT CONTAMINATE WATER SUPPLY, FOOD OR FEED BY STORAGE OR DISPOSAL. WASTES RESULTING FROM USE OF THIS PRODUCT MAY BE DISPOSED OF ON-SITE OR AT AN APPROVED WASTE DISPOSAL FACILITY. TREATMENT, STORAGE OR TRANSPORTATION MUST BE IAW APPLICABLE FEDERAL, STATE & LOCAL REGULATIONS. DO NOT FLUSH TO SURFAC E WATER OR SANITARY SEWER. =================== MSDS Transport Information =================== Transport Information:DOT/IMO PROPER SHIPPING NAME:NOT REGULATED. ===================== Regulatory Information ===================== SARA Title III Information:SARA TITLE III HAZARD CLASSIFICATION SECTIONS 311/312. ACUTE: YES. CHRONIC: YES. FIRE: NO. REACTIVITY: NO. PRESSURE: NO. BROMACIL (5-BROMO-3-SEC-BUTYL-6-METHYLURACIL)* DISCOLSURE AS A TOXIC CHEMICAL I S REQUIRED UNDER SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS & REAUTHORIZATION ACT OF 1986 & 40 CFR PART 372. Federal Regulatory Information:EPA REG NO IS 352-287. IN THE U.S. THIS PRODUCT IS REGULATED BY THE EPA UNDER THE FEDERAL INSECTICIDE, FUNGICIDE & RODENTICIDE ACT. IT IS A VIOLATION OF FEDERAL LAW TO USE THIS PRODUCT IN A MANNER INC ONSISTENT WITH ITS LABELING. State Regulatory Information:NONE SPECIFIED BY MANUFACTURER. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.