EXXONMOBIL CHEMICAL COMPANY A DIVISION OF EXXON MOBIL CORP. -- TOLUENE -- 6810-00-290-0046
===================== Product Identification ===================== Product ID:TOLUENE MSDS Date:04/01/2000 FSC:6810 NIIN:00-290-0046 Status Code:A === Responsible Party === Company Name:EXXONMOBIL CHEMICAL COMPANY A DIVISION OF EXXON MOBIL CORP. Box:3272 City:HOUSTON State:TX ZIP:77253-3272 Country:US Info Phone Num:800-726-2015 Emergency Phone Num:(800)424-9300 Resp. Party Other MSDS Num.:92931650 Chemtrec Ind/Phone:(800)424-9300 CAGE:TO602 === Contractor Identification === Company Name:CHEMICAL SPECIALISTS AND DEVELOPMENT INC Address:2210 HACKBERRY LN Box:687 City:CONROE State:TX ZIP:77305 Country:US Phone:409-756-1065 Contract Num:SP0450-01-M-ZG95 CAGE:4N760 Company Name:EXXONMOBIL CHEMICAL COMPANY A DIVISION OF EXXON MOBIL CORP. Address:Box:3272 City:HOUSTON State:TX ZIP:77253-3272 Country:US Phone:800-726-2015 CAGE:TO602 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 = Wt:100. OSHA PEL:SEE TABLE Z-2 ACGIH TLV:188 MG/M3;50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO DATA PROVIDED BY MANUFACTURER Health Hazards Acute and Chronic:EYE: IRRITATING, BUT DOES NOT INJURE EYE TISSUE. SKIN: FREQUENT OR PROLONGED CONTACT MAY IRRITATE & CAUSE DERMATITIS. OCCASIONAL BRIEF CONTACT WITH THE LIQUID WILL NOT RESULT IN SIGNIFICANT IRRITATION UNLESS EVAPORATION IS IMPEDED. SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS CONDITION. INHALATION: HIGH VAPOR/AEROSOL CONCENTRATIONS ARE IRRITATING TO THE EYES & THE RESPIRATORY TRACT, MAY CAUSE HEADACHES, DIZZINESS, ANESTHESIA, DROWSINESS, UNCONSCIOUSNESS, CENTRAL NERVOUS SYSTEM EFFECTS, BRAIN DAMAGE & POSSIBLY DEATH. INGESTION: SMALL AMOUNTS OF THIS PRODUCT ASPIRATED INTO THE RESPIRATORY S YSTEM MAY CAUSE PULMONARY INJURY. Explanation of Carcinogenicity:NO DATA PROVIDED BY MANUFACTURER Effects of Overexposure:EYE: IRRITATING, BUT DOES NOT INJURE EYE TISSUE. SKIN: FREQUENT OR PROLONGED CONTACT MAY IRRITATE & CAUSE DERMATITIS. OCCASIONAL BRIEF CONTACT WITH THE LIQUID WILL NOT RESULT IN SIGNIFICANT IRRITATION UNLESS EVAPORATION IS IMPEDED. INHALATION: HIGH VAPOR/AEROSOL CONCENTRATIONS (GREATER THAN APPROXIMATELY 1000 PPM) ARE IRRITATING TO THE EYES & THE RESPIRATORY TRACT, MAY CAUSE HEADACHES, DIZZINESS, ANESTHESIA, DROWSINESS, UNCONSCIOUSNESS, CENTRAL NERVOUS SYSTEM EFFECTS, BRAIN DAMAGE & POSSIBLY DEATH. INGESTION: SMALL AMOUNTS OF THIS PRODUCT ASPIRATED INTO THE RESPIRATORY Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS CONDITION. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH EYES WITH LARGE AMOUNTS OF WATER UNTIL IRRITATION SUBSIDES. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. SKIN: FLUSH WITH LARGE AMOUNTS OF WATER; USE SOAP IF AVAILABLE. REMOVE GROSSLY CON TAMINATED CLOTHING, INCLUDING SHOES, AND LAUNDER BEFORE REUSE. INHALATION: USING PROPER RESPIRATORY PROTECTION, IMMEDIATELY REMOVE THE AFFECTED VICTIM FROM EXPOSURE. ADMINISTER ARTIFICIAL RESPIRATION IF BREATHING IS STOPPED. KEEP AT REST. CALL FOR PROMPT MEDICAL ATTENTION. INGESTION: IF SWALLOWED, DO NOT INDUCE VOMITING. KEEP AT REST. GET PROMPT MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=7.2C, 45.F TYPICAL Autoignition Temp:=552.2C, 1026.F Autoignition Temp Text:APPROX Lower Limits:1.4 Upper Limits:7.4 Extinguishing Media:USE WATER SPRAY TO COOL FIRE EXPOSED SURFACES AND TO PROTECT PERSONNEL. SHUT OFF "FUEL" TO FIRE. IF A LEAK OR SPILL HAS NOT IGNITED, USE WATER SPRAY TO DISPERSE THE VAPORS. Fire Fighting Procedures:USE WATER SPRAY TO COOL FIRE EXPOSED SURFACES AND TO PROTECT PERSONNEL. SHUT OFF "FUEL" TO FIRE. IF A LEAK OR SPILL HAS NOT IGNITED, USE WATER SPRAY TO DISPERSE THE VAPORS. EITHER ALLOW FIRE TO BURN U NDER CONTROLLED CONDITIONS OR EXTINGUISH WITH FOAM OR DRY CHEMICAL. TRY TO COVER LIQUID SPILL WITH FOAM. Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID, CAN RELEASE VAPORS THAT FORM FLAMMABLE MIXTURES AT TEMPERATURES AT OR ABOVE THE FLASHPOINT. TOXIC GASES WILL FORM UPON COMBUSTION. STATIC DISCHARGE, MATERIAL CAN ACCUMULATE STATIC CH ARGES WHICH CAN CAUSE AN INCENDIARY ELECTRICAL DISCHARGE. "EMPTY" CONTAINERS RETAIN PRODUCT RESIDUE (LIQUID &/OR VAPOR) ================== Accidental Release Measures ================== Spill Release Procedures:LAND SPILL: ELIMINATE SOURCES OF IGNITION. PREVENT ADDITIONAL DISCHARGE OF MATERIAL, IF POSSIBLE TO DO SO WITHOUT HAZARD. FOR SMALL SPILLS IMPLEMENT CLEANUP PROCEDURES; FOR LARGE SPILLS IMPLEMENT CLEA NUP PROCEDURES AND, IF IN PUBLIC AREA, KEEP PUBLIC AWAY AND ADVISE AUTHORITIES. ALSO, IF THIS PRODUCT IS SUBJECT TO CERCLA REPORTING NOTIFY THE NATIONAL RESPONSE CENTER. PREVENT LIQUID FROM ENTERING Neutralizing Agent:NO DATA PROVIDED BY MANUFACTURER ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. HANDLE AND OPEN CONTAINERS WITH CARE. STORE IN A COOL, WELL VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIALS. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR OTHER SOURCES O F IGNITION. PROTECT MATERIAL FROM DIRECT SUNLIGHT. Other Precautions:MATERIAL WILL ACCUMULATE STATIC CHARGES WHICH MAY CAUSE AN ELECTRICAL SPARK (IGNITION SOURCE). USE PROPER BONDING &/OR GROUNDING PROCEDURES. DO NOT PRESSURIZE, CUT, HEAT, OR WELD CONTAINERS. EMPTY PRO DUCT CONTAINERS MAY CONTAIN PRODUCT RESIDUE. DO NOT REUSE EMPTY CONTAINERS WITHOUT COMMERCIAL CLEANI NG OR RECONDITIONING ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE CONCENTRATIONS IN AIR MAY EXCEED THE LIMITS GIVEN IN THIS SECTION AND ENGINEERING, WORK PRACTICE OR OTHER MEANS OF EXPOSURE REDUCTION ARE NOT ADEQUATE, NIOSH APPROVED RESPIRATOR MAY BE NECESSA RY TO PREVENT OVEREXPOSURE BY INHALATION. Ventilation:THE USE OF LOCAL EXHAUST VENTILATION IS RECOMMENDED TO CONTROL PROCESS EMISSIONS NEAR THE SOURCE. LABORATORY SAMPLES SHOULD BE HANDLED IN A LAB HOOD. Protective Gloves:CHEMICAL RESISTANT GLOVES. Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS Other Protective Equipment:LONG SLEEVES. Work Hygienic Practices:REMOVE GROSSLY CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. Supplemental Safety and Health PROVIDE MECHANICAL VENTILATION OF CONFINED SPACES. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:230F - 232F Melt/Freeze Pt:<-60.C, -76.F Vapor Pres:22 @68F APPROXIMATE Vapor Density:3.20 Spec Gravity:0.87 @ 60F Viscosity:0.7 @ 77F APPROXIMATE Evaporation Rate & Reference:2.4 APPROXIMATE Solubility in Water:0.05 @ 77F CALCULATED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, CONCENTRATED NITRIC OR SULPHURIC ACID, HALOGENS, OR MOLTEN SULPHUR. Stability Condition to Avoid:NOT APPLICABLE. Hazardous Decomposition Products:NONE Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:NO DATA PROVIDED BY MANUFACTURER ===================== Ecological Information ===================== Ecological:NO SPECIFIC ECOLOGICAL DATA ARE AVAILABLE FOR THIS PRODUCT. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT AN EXPERT ON DISPOSAL OF RECOVERED MATERIAL AND ENSURE CONFORMITY TO LOCAL DISPOSAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOT SHIPPING DESCRIPTION: TOLUENE, 3, UN1294, II. ===================== Regulatory Information ===================== SARA Title III Information:UNDER THE PROVISIONS OF TITLE III, SECTIONS 311/312 OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT, THIS PRODUCT IS CLASSIFIED INTO THE FOLLOWING HAZARD CATEGORIES: IMMEDIATE HEALTH, DELAYED HEAL TH, FIRE. THIS INFORMATION MAY BE SUBJECT TO THE PROVISIONS OF THE COMMUNITY RIGHT-TO-KNOW REPORTING REQUIREMENTS (40 CFR 370) IF THRESHOLD QUANTITY CRITERIA ARE MET. THE PRODUCT CONTAINS THE FOLLOWIN G SECTION 313 REPORTABLE INGREDIENTS: TOLUENE, CAS# 108-88-3, 100%. Federal Regulatory Information:TSCA: THIS PRODUCT IS LISTED ON THE TSCA INVENTORY AS A UVCB CHEMICAL AT CAS# 108-88-3. CERCLA: IF THE REPORTABLE QUANTITY OF THIS PRODUCT IS ACCIDENTLY SPILLED, THE ICIDENT IS SUBJECT TO THE PROVISIO NS OF CERCLA & MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER BY CALLING 800-424-8802. THE REPORTABLE SPILL QUANTITY OF THIS PRODUCT IS 1,000 POUNDS. IT CONTAINS: TOLUENE. State Regulatory Information:NO DATA PROVIDED BY MANUFACTURER ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.